This book provides a comprehensive description of various slab waveguide structures ranged from graded-index waveguide to symmetrical metal-cladding waveguide. In this book, the transfer Matrix method is developed and applied to analyze the simplest case and the complex generalizations. A novel symmetrical metal-cladding waveguide structure is proposed and systematically investigated for several issues of interest, such as biochemical sensing, Goos-Hänchen shift and the slow light effect, ...